Econ. Environ. Geol. 2005; 38(3): 335-346

Published online June 30, 2005

© THE KOREAN SOCIETY OF ECONOMIC AND ENVIRONMENTAL GEOLOGY

Sulfate Reduction and Origin of Organic Matter in the Ulleung Basin, East Sea

Myong-Ho Park1, Ji-Hoon Kim2*, Byong-Jae Ryu2, Il-Soo Kim3, Youngju Lee2 and Ho-Wan Chang4

1Technical Department, Korea National Oil Corporation, Anyang 431-711, Korea
2Petroleum and Marine Resources Research Division, Korea Institute of Geoscience and Mineral Resources, Daejeon 305-350, Korea
3Domestic Exploration Team I, Korea National Oil Corporation, Anyang 431-711, Korea
4School of Earth and Environmental Science, Seoul National University, Seoul 151-742, Korea

Correspondence to :

Ji-Hoon Kim

save@kigam.re.kr

Received: December 22, 2004; Accepted: May 4, 2005

Abstract

In this study, core sediments and pore water were analysed to identify the origin of organic matter and gas in late Quaternary sediments from the northwestern Ulleung Basin of the East Sea. C/N and C/S ratios in the sediments show that the organic matter in the study area originated predominantly from marine algae. However, the results of Rock-Eval pyrolysis indicate that the organic matter has an origin of the land-plant (Type III), locating in the immature stage. These different results might be due to the heavy oxidizing of the organic matter during sinking down to the seafloor or after deposition in the sediments. Concentration of sulfate in the pore water decreases gradually with core depth, while concentration of CH4 increases gradually with core depth. This indicates that sulfate reduction and methanogenesis occurred actively in the sediments. Also, it is likely that the compositions of CH4 are characterized as a more biogenic origin, mostly caused by microbial activity, rather than a thermogenic one.

Keywords core sediment, pore water, sulfate reduction, methanogenesis, late Quaternary, Ulleung Basin, East Sea

Article

Econ. Environ. Geol. 2005; 38(3): 335-346

Published online June 30, 2005

Copyright © THE KOREAN SOCIETY OF ECONOMIC AND ENVIRONMENTAL GEOLOGY.

Sulfate Reduction and Origin of Organic Matter in the Ulleung Basin, East Sea

Myong-Ho Park1, Ji-Hoon Kim2*, Byong-Jae Ryu2, Il-Soo Kim3, Youngju Lee2 and Ho-Wan Chang4

1Technical Department, Korea National Oil Corporation, Anyang 431-711, Korea
2Petroleum and Marine Resources Research Division, Korea Institute of Geoscience and Mineral Resources, Daejeon 305-350, Korea
3Domestic Exploration Team I, Korea National Oil Corporation, Anyang 431-711, Korea
4School of Earth and Environmental Science, Seoul National University, Seoul 151-742, Korea

Correspondence to:

Ji-Hoon Kim

save@kigam.re.kr

Received: December 22, 2004; Accepted: May 4, 2005

Abstract

In this study, core sediments and pore water were analysed to identify the origin of organic matter and gas in late Quaternary sediments from the northwestern Ulleung Basin of the East Sea. C/N and C/S ratios in the sediments show that the organic matter in the study area originated predominantly from marine algae. However, the results of Rock-Eval pyrolysis indicate that the organic matter has an origin of the land-plant (Type III), locating in the immature stage. These different results might be due to the heavy oxidizing of the organic matter during sinking down to the seafloor or after deposition in the sediments. Concentration of sulfate in the pore water decreases gradually with core depth, while concentration of CH4 increases gradually with core depth. This indicates that sulfate reduction and methanogenesis occurred actively in the sediments. Also, it is likely that the compositions of CH4 are characterized as a more biogenic origin, mostly caused by microbial activity, rather than a thermogenic one.

Keywords core sediment, pore water, sulfate reduction, methanogenesis, late Quaternary, Ulleung Basin, East Sea

    KSEEG
    Oct 29, 2024 Vol.57 No.5, pp. 473~664

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